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ester pyrolysis : ウィキペディア英語版
ester pyrolysis
Ester pyrolysis in organic chemistry is a vacuum pyrolysis reaction converting esters containing a β-hydrogen atom into the corresponding carboxylic acid and the alkene. The reaction is an Ei elimination.
Examples are the synthesis of acrylic acid from ethyl acrylate at 590 °C,〔Organic Syntheses, Coll. Vol. 3, p.30 (1955); Vol. 29, p.2 (1949). (Link )〕 the synthesis of 1,4-pentadiene from 1,5-pentanediol diacetate at 575 °C 〔Organic Syntheses, Coll. Vol. 4, p.746 (1963); Vol. 38, p.78 (1958). (Link )〕 or the construction of a cyclobutene framework at 700 °C 〔Organic Syntheses, Coll. Vol. 5, p.235 (1973); Vol. 43, p.17 (1963). (Link )〕
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==References==

ester pyrolysis is a syn elimination

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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